Heat ½ tablespoon avocado oil in a large skillet over medium-high heat. Add the chicken thighs and sear on both sides until golden brown, about 2-3 minutes per side (they won't yet be all the way cooked through). Remove to a plate.
In the same skillet, add the remaining tablespoon of oil, onion and pepper and sauté until softened, about 5-7 minutes. Add garlic and cook for an additional 1 minute.
Stir in the rice, crushed tomatoes, cherry tomatoes, balsamic vinegar, water, salt, pepper, and dried basil. Nestle the chicken thighs into the rice mixture.
Reduce heat to medium-low, cover, and simmer for 20-25 minutes, or until rice is tender and chicken is cooked through, stirring occasionally (~every 5 minutes).
Remove from heat and let rest for 5 minutes. Garnish with fresh basil leaves before serving and enjoy.
Notes
LeftoversStore leftovers in an airtight container in the refrigerator for up to 4 days or freeze for up to 3 months. Rewarm in the microwave until heated through.